e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Aliphatische Azoverbindungen, IV1 Eine neue Synthese für tert.??Azoalkane

W Duismann, HD Beckhaus…

Index: Duismann,W. et al. Justus Liebigs Annalen der Chemie, 1974 , p. 1348 - 1356

Full Text: HTML

Citation Number: 3

Abstract

Organisch-Chemisches Institut der Universitat, D-44 Munster, Orleansring 23 und Chemisches Laboratorium der Universitat, D-78 Freiburg, AlbertstraBe 2 I Eingegangen am 10. Oktober 1973 ... Eine ergiebige, einfach und im grol3en MaBstab durchzufuhrende Synthese fur tert.-Azoalkane 3 aus den gut zuganglichen Chlorazoverbindungen 2 rnit Trialkyl- oder Triphenylaluminium wird beschrieben. Die Anwendungsbreite der Reaktion wird diskutiert.

2,4-dimethyl-3-pentanone [2-methyl-1-(1-methylethyl)propylidene]hydrazone Structure

2,4-dimethyl-3-...

~%

bis(2,3,4-trimethylpentan-3-yl)diazene Structure

bis(2,3,4-trime...

bis-(1-chloro-1-isopropyl-2-methyl-propyl)-diazene Structure

bis-(1-chloro-1...

trimethylaluminum Structure

trimethylaluminum

~%

bis(2,3,4-trimethylpentan-3-yl)diazene Structure

bis(2,3,4-trime...

Triethylaluminum Structure

Triethylaluminum

N/A Structure

~%

bis(5-ethylnonan-5-yl)diazene Structure

bis(5-ethylnona...

bis-(1-ethyl-3,3-dimethyl-butylidene)-hydrazine Structure

bis-(1-ethyl-3,...

~%

bis(3-ethyl-2-methylpentan-3-yl)diazene Structure

bis(3-ethyl-2-m...

bis-(1-chloro-1-ethyl-2-methyl-propyl)-diazene Structure

bis-(1-chloro-1...

Triethylaluminum Structure

Triethylaluminum

~%

bis(3-ethyl-2-methylpentan-3-yl)diazene Structure

bis(3-ethyl-2-m...

Diazene,1,2-bis(1-chloro-1-methylethyl)- Structure

Diazene,1,2-bis...

Triisobutylaluminum Structure

Triisobutylaluminum

~%

bis(2,4-dimethylpentan-2-yl)diazene Structure

bis(2,4-dimethy...

bis-(1,3-dimethyl-butylidene)-hydrazine Structure

bis-(1,3-dimeth...

~%

bis(3,5-dimethylhexan-3-yl)diazene Structure

bis(3,5-dimethy...

bis(2-chloro-4-methylpentan-2-yl)diazene Structure

bis(2-chloro-4-...

Triethylaluminum Structure

Triethylaluminum

~%

bis(3,5-dimethylhexan-3-yl)diazene Structure

bis(3,5-dimethy...

(E)-N-[(Z)-butan-2-ylideneamino]butan-2-imine Structure

(E)-N-[(Z)-buta...

~%

bis(3-methylpentan-3-yl)diazene Structure

bis(3-methylpen...

α,α'-dichloroazo compound Structure

α,α'-dichloroaz...

Triethylaluminum Structure

Triethylaluminum

~%

bis(3-methylpentan-3-yl)diazene Structure

bis(3-methylpen...

Diazene,1,2-bis(1-chloro-1-methylethyl)- Structure

Diazene,1,2-bis...

Triethylaluminum Structure

Triethylaluminum

~%

2,2'-dimethyl-2,2'-azobutane Structure

2,2'-dimethyl-2...

3,6-di-naphthalen-2-yl-1,2-dihydro-[1,2,4,5]tetrazine Structure

3,6-di-naphthal...

~%

AZO-TERT-OCTANE Structure

AZO-TERT-OCTANE

bis-(1-chloro-1,3,3-trimethyl-butyl)-diazene Structure

bis-(1-chloro-1...

trimethylaluminum Structure

trimethylaluminum

~%

AZO-TERT-OCTANE Structure

AZO-TERT-OCTANE

1,2-bis(5,5-dimethylhexan-3-ylidene)hydrazine Structure

1,2-bis(5,5-dim...

~%

bis(3-ethyl-5,5-dimethylhexan-3-yl)diazene Structure

bis(3-ethyl-5,5...

tri(propan-2-yl)alumane Structure

tri(propan-2-yl...

N/A Structure

~%

bis(5-propan-2-ylnonan-5-yl)diazene Structure

bis(5-propan-2-...

bis-(1,2-dimethyl-propylidene)-hydrazine Structure

bis-(1,2-dimeth...

~%

bis(2,3-dimethylbutan-2-yl)diazene Structure

bis(2,3-dimethy...

1,2-bis(2-chloro-3-methylbutan-2-yl)diazene Structure

1,2-bis(2-chlor...

trimethylaluminum Structure

trimethylaluminum

~%

bis(2,3-dimethylbutan-2-yl)diazene Structure

bis(2,3-dimethy...

tris(1,1-dimethylethyl)-Aluminum Structure

tris(1,1-dimeth...

N/A Structure

~%

bis(5-tert-butylnonan-5-yl)diazene Structure

bis(5-tert-buty...

di(tert-butyl-methyl)ketazine Structure

di(tert-butyl-m...

~%

bis(2,2,3-trimethylpentan-3-yl)diazene Structure

bis(2,2,3-trime...

bis-(1-chloro-1,2,2-trimethyl-propyl)-diazene Structure

bis-(1-chloro-1...

Triethylaluminum Structure

Triethylaluminum

~%

bis(2,2,3-trimethylpentan-3-yl)diazene Structure

bis(2,2,3-trime...

3,6-di-naphthalen-2-yl-1,2-dihydro-[1,2,4,5]tetrazine Structure

3,6-di-naphthal...

~%

bis(3,5,5-trimethylhexan-3-yl)diazene Structure

bis(3,5,5-trime...

bis-(1-chloro-1,3,3-trimethyl-butyl)-diazene Structure

bis-(1-chloro-1...

Triethylaluminum Structure

Triethylaluminum

~%

bis(3,5,5-trimethylhexan-3-yl)diazene Structure

bis(3,5,5-trime...

Diazene,1,2-bis(1-chloro-1-methylethyl)- Structure

Diazene,1,2-bis...

Tri-n-octylaluminum Structure

Tri-n-octylaluminum

~%

bis(2-methyldecan-2-yl)diazene Structure

bis(2-methyldec...

2,4-dimethyl-3-pentanone [2-methyl-1-(1-methylethyl)propylidene]hydrazone Structure

2,4-dimethyl-3-...

~%

bis(3-ethyl-2,4-dimethylpentan-3-yl)diazene Structure

bis(3-ethyl-2,4...

bis-(1-chloro-1-isopropyl-2-methyl-propyl)-diazene Structure

bis-(1-chloro-1...

Triethylaluminum Structure

Triethylaluminum

~%

bis(3-ethyl-2,4-dimethylpentan-3-yl)diazene Structure

bis(3-ethyl-2,4...

bis-(1-ethyl-2,2-dimethyl-propylidene)-hydrazine Structure

bis-(1-ethyl-2,...

~%

bis(3-ethyl-2,2-dimethylpentan-3-yl)diazene Structure

bis(3-ethyl-2,2...

N/A Structure

Triethylaluminum Structure

Triethylaluminum

~%

bis(3-ethyl-2,2-dimethylpentan-3-yl)diazene Structure

bis(3-ethyl-2,2...

Clocking Tertiary Cyclopropylcarbinyl Radical Rearrangements...

[Duismann,W. et al. Tetrahedron Letters, 1974 , p. 265 - 268]