Designer dendrimers: branched oligosulfonimides with controllable molecular architectures

…, V Gramlich, R Kandre, I Zhun, T Felder…

Index: Lukin, Oleg; Gramlich, Volker; Kandre, Ramchandra; Zhun, Igor; Felder, Thorsten; Schalley, Christoph A.; Dolgonos, Grigoriy Journal of the American Chemical Society, 2006 , vol. 128, # 27 p. 8964 - 8974

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Citation Number: 32

Abstract

The synthesis of “designer” dendrimers and dendrons with sulfonimide units at every branching point is reported. The synthesis is based on a series of (regio) selective functionalization reactions of amines and sulfonamides allowing precise control of the dendrimers' shape, the number of branches in each generation, and their peripheral decoration with functional groups. In principle, structurally different branches can be ...