Photophysical Behavior of Open-Shell, First-Row Transition Metal meso-Tetraphenyltetrabenzoporphyrins: Insights from Experimental and Theoretical Studies†

…, AV Soldatova, MAJ Rodgers

Index: Soldatova, Alexandra V.; Kim, Junhwan; Rosa, Angela; Ricciardi, Giampaolo; Kenney, Malcolm E.; Rodgers, Michael A. J. Inorganic Chemistry, 2008 , vol. 47, # 10 p. 4275 - 4289

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Citation Number: 10

Abstract

The ground and excited state properties of two metallo-tetraphenyltetrabenzoporphyrins (MTPTBP) have been investigated by a combination of DFT/TDDFT and transient absorption spectrometry to draw a complete picture of the excited state deactivation. The Cu (II) and Co