Interaction of N, N-dimethylperfluoroarylamines with nitric and nitrous acids

…, M Schelvis, M Lieb, KV Dvornikova, IO Ol'ga

Index: Platonov, Vyacheslav E.; Haas, Alois; Schelvis, Meinolf; Lieb, Max; Dvornikova, Kira V.; Osina, Ol'ga I. Journal of Fluorine Chemistry, 2002 , vol. 116, # 1 p. 3 - 8

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Citation Number: 3

Abstract

N, N-Dimethylpentafluoroaniline enters easily into reactions with a mixture of nitric and sulphuric acids or nitric acid with conversion of the side chain. In the reactions with mixtures of HNO3 and H2SO4, the formation of N-nitroso-N-methyl and N-nitro-N- methylpentafluoroanilines is observed. The ratio of these products was found to depend on the ratio of the acids: the formation of N-nitro-N-methylpentafluoroaniline increases with ...