Journal of Chemical Research

Low-valent titanium induced reductive deprotection of oximes

X Fan, X Zhanga, Y Zhang

Index: Fan, Xuesen; Zhang, Xinying; Zhang, Yongmin Journal of Chemical Research, 2004 , # 4 p. 290 - 291

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Abstract

Oximes are extensively used as derivatives for the protection, purification and characterisation of aldehydes and ketones. In addition, their availability from non-carbonyl compounds, such as by nitrosation of an active methylene group,1 nitrosation of -halocarbonyl compounds2 and condensation of nitroalkenes with aldehydes,3 provides an alternate pathway to carbonyl compounds. Thus, the development of procedures for the effective cleavage of oximes to ...

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