The Journal of Organic Chemistry

Preparation of allenyl esters

DG Oelberg, MD Schiavelli

Index: Oelberg,D.G.; Schiavelli,M.D. Journal of Organic Chemistry, 1977 , vol. 42, # 10 p. 1804 - 1806

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Citation Number: 39

Abstract

The formation of allenyl acetates and substituted benzoates by symmetry-allowed thermal rearrangement and by metalcatalyzed rearrangement is well documented. 2 The formation of allenyP phosphonates, phosphinates, and phosphine oxides from thermal rearrangement of the corresponding propargyl phosphites, phosphonites, and phosphinites, respectively, is also well kn~ wn.~*-c We wish to report the extension of these reactions to the preparation ...