A novel photocatalytic process of amine N-alkylation by platinized semiconductor particles suspended in alcohols

B Ohtani, H Osaki, S Nishimoto…

Index: Ohtani, Bunsho; Osaki, Haruyoshi; Nishimoto, Sei-ichi; Kagiya, Tsutomu Journal of the American Chemical Society, 1986 , vol. 108, # 2 p. 308 - 310

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Citation Number: 77

Abstract

" Amine (100 pmol), alcohol (5.0 cm3), and catalyst (52.5 mg) were placed in a test tube and irradiated under Ar by 400-W high-pressure mercury arc. Based on the starting amine.'Molar ratio of H2 used for N-alkylation (reactions 3 and 4). dQuantum efficiency was evaluated as ca. 2% by using a Blak-Ray 5-221 Ultraviolet Meter on the assumption that the incident light consists of photons at 365 nm.'A 5.0-mg portion of Ti02/Pt catalyst was used. fCdS with 5 ...