Tetrahedron letters

Grignard reagents selective attack to nitroarenic function in the presence of other electrophilic groups

G Bartoli, M Bosco, R Dalpozzo

Index: Bartoli, G.; Bosco, M.; Dalpozzo, R. Tetrahedron Letters, 1985 , vol. 26, # 1 p. 115 - 118

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Citation Number: 25

Abstract

Abstract Exclusive alkylation of the nitroarenic system takes place in competitive reactions of RMgX with nitrobenzene and various electrophiles such as ketones, esters, cyano-and iodo- derivatives and in reactions with some functionalized nitrobenzenes, only aldehydes show comparable reactivity.