Synthesis of esters of 3, 3-dicyano-2-(trifluoromethyl) acrylic acid and their reactions with arylamines

VY Tyutin, ND Chkanikoc, AF Kolomietz…

Index: Tyutin, V. Y.; Chkanikov, N. D.; Kolomietz, A. F.; Fokin, A. V. Journal of Fluorine Chemistry, 1991 , vol. 51, # 3 p. 323 - 334

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Citation Number: 17

Abstract

Abstract Methyl and ethyl esters of 3, 3-dicyano-2-(trifluoromethyl) acrylic acid (I) and (II) have been obtained by condensation of methyl and ethyl trifluoropyruvate with malononitrile. The C-alkylation reactions of anilines and possibilities of forming heterocyclic compounds with other types of arylamines have been systematically studied for alkene-esters (I) and (II).