Tetrahedron

Chiral lipophilic ligands. 2. Cu (II)-Mediated transport of α-amino acids across a bulk chloroform membrane

P Scrimin, P Tecilla, U Tonellato

Index: Scrimin, Paolo; Tecilla, Paolo; Tonellato, Umberto Tetrahedron, 1995 , vol. 51, # 1 p. 217 - 230

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Citation Number: 29

Abstract

A number of achiral (1–4) and chiral (5–10) 1, 2-diamino ethane derivatives bearing on one or both nitrogen atoms long paraffinic chains have been synthesized and successfully tested as carriers for the transport of Cu (II) and α-amino acids across a bulk chloroform membrane from a buffered (pH= 5.5) source phase to a receiving solution of EDTA. This, being a highly hydrophilic ligand with an affinity for Cu (II) several order of magnitude larger than that of ...