Réaction de dérivés à liaison germanium-azote (germylamines, cyclogermazanes et germa-imines transitoires) avec la di-t-butyl-3, 5-orthoquinone

M Rivière-Baudet, P Rivière, A Khallaayoun…

Index: Riviere-Baudet, M.; Riviere, P.; Khallaayoun, A.; Satge, J.; Rauzy, K. Journal of Organometallic Chemistry, 1988 , vol. 358, p. 77 - 94

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Citation Number: 16

Abstract

Abstract Several germanium-nitrogen compounds were treated with 3, 5-di-t- butylorthoquinone (1). In the case of the germylamines R 3 GeNMe 2 (R= Et, Ph), 1, 2 and 1, 4 adducts were formed, as shown by 1 H NMR spectroscopy. The thermally unstable 1, 4 adduct, decomposes with nitrene elimination to give 2, 2-dialkyl or 2, 2-diaryl (6, 8-di-t-butyl)- 4, 5-benzo-2-germa-1, 3-dioxolane.