Selective formation of imines by aerobic photocatalytic oxidation of amines on TiO2

X Lang, H Ji, C Chen, W Ma…

Index: Lang, Xianjun; Ji, Hongwei; Chen, Chuncheng; Ma, Wanhong; Zhao, Jincai Angewandte Chemie - International Edition, 2011 , vol. 50, # 17 p. 3934 - 3937

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Citation Number: 194

Abstract

Imine derivatives are important building blocks for the synthesis of fine chemicals and pharmaceuticals.[1] Generally, their synthesis involves condensation of an amine and a carbonyl compound. To circumvent the problem caused by the excessively active nature of ketones or aldehydes, an alternative strategy for the direct oxidation of amines has attracted much interest.[2] Dioxygen, or more preferably dioxygen in the air, embodies the ...