Tetrahedron

2-(2-Nitroethyl)-1, 3-dioxolane as reagent for 3-oxopropyl anion synthon: a new route to jasmonoid and prostaglandin intermediates

G Rosini, R Ballini, M Petrini, P Sorrenti

Index: Rosini, Goffredo; Ballini, Roberto; Petrini, Marino; Sorrenti, Pietro Tetrahedron, 1984 , vol. 40, # 19 p. 3809 - 3814

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Citation Number: 19

Abstract

2-(2-Nitroethyl)-l, 3-dioxolane 18 a versatile reagent for 3-oxopropyl anion synthon. New methodology, based on nitro-aldol condensation, oxidation and direct or indirect denitration sequence is developed for the conversion of 2-(2-nitroethyl)-l, 3 dioxolane into (Z)-l, 4- ...