The Journal of Organic Chemistry

Polynitroalykyl ethers

V Grakauskas

Index: Grakauskas,V. Journal of Organic Chemistry, 1973 , vol. 38, p. 2999 - 3004

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Citation Number: 14

Abstract

Polynitroethyl ethers were prepared by nitration of the corresponding oximes. Thus, nitration of (2-fluoro-2, 2-dinitroethoxy) acetaldoxime followed by oxidation of the nitroso intermediate yielded 2-fluoro-2, 2-dinitroethyl 2, Bdinitroethyl ether (1). Fluorination and chlorination of 1 yielded bis (2-fluoro-2, Pdinitroethyl) and Zchloro-2, 2-dinitroethyl Zfluoro-2, 2-dinitroethyl ether, respectively. Formaldehyde and 1 yielded 3-(2-fluoro-2, 2-dinitroethoxy> 2, ...