Electron??Poor Olefin Polymerization Catalysts Based on Semi??Fluorinated Bis (phosphane) s

R Wursche, T Debaerdemaeker…

Index: Wursche, Roland; Debaerdemaeker, Tony; Klinga, Martti; Rieger, Bernhard European Journal of Inorganic Chemistry, 2000 , # 9 p. 2063 - 2070

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Citation Number: 19

Abstract

Abstract Two semi-fluorinated bis (phosphane) s, P, P′-(1, 2-ethanediyl) bis [bis (2, 4, 5- trifluorophenyl) phosphane](3a), P, P′-(1, 2-ethanediyl) bis [bis (2, 4-difluorophenyl) phosphane](3b), and their corresponding Pd II-and Pt II-dichloro complexes (4a, b and 6a, b) have been synthesized. Complexation of P, P′-(1, 2-ethanediyl) bis {bis [3, 5-di (trifluoromethyl) phenyl] phosphane}(3c) and P, P′-(1, 2-ethanediyl) bis [bis ( ...