Halomethyl-metal compounds. XLVI. Reaction of phenyl (bromodichloromethyl) mercury with heteroatom cumulenes

D Seyferth, R Damrauer, HM Shih…

Index: Seyferth,D. et al. Journal of Organic Chemistry, 1971 , vol. 36, p. 1786 - 1789

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Citation Number: 10

Abstract

Results Successful CXZ transfer to a CK bond via PhHgCXa reagents to give an aziridine is possible when the nucleophilic character of the nitrogen atom has been significantly decreased. 8 Thus, compounds of type RN= CC12 could be converted to C- perchloroaziridines in good yield by reaction with phenyl (bromodichloromethyl)-mercury, but imines of type RN= CHR'and RN= CR'Z appeared to react with these mercury ...