Journal of the American Chemical Society

Magnetic interaction between the triplet centers in ethynylenebis (phenylnitrenes) and 1, 3-butadiyne-1, 4-diylbis (phenylnitrenes)

S Murata, H Iwamura

Index: Murata, Shigeru; Iwamura, Hiizu Journal of the American Chemical Society, 1991 , vol. 113, # 15 p. 5547 - 5556

Full Text: HTML

Citation Number: 59

Abstract

Abstract: The magnetic interaction of the two triplet phenylnitrene units linked together through an acetylene or a diacetylene linkage has been investigated by ESR spectroscopy. Two regioisomeric (meta, para'and meta, meta') diazides of 1, 2-diphenylacetylene 12a and 1, 4-diphenyI-l, 3-butadiyne 13a were prepared and photolyzed in a 2-methyltetrahydrofuran glass at IO K to give the corresponding dinitrenes 12n and 1311. The m, p'-dinitrenes of ...