Synthesis And Reactions Of Sterically Hindered α-Naphthyl-And Cyclohexylantimony (V) Derivatives

S Agnihotri, P Raj, K Singhal

Index: Agnihotri, Santosh; Raj, Prem; Singhal, Kiran Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 2002 , vol. 32, # 2 p. 399 - 417

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Citation Number: 5

Abstract

ABSTRACT Interhalogen and halo-pseudohalogens IX (X= Cl, Br, N3, NCO),(SCN) 2, S and TeCl4 add oxidatively to (α-C10H7) 3Sb to afford (α-C10H7) 3SbIX,(α-C10H7) 3 Sb (SCN) 2,(α-C10H7) 3 SbS and (α-C10H7) 3SbCl2, respectively. Reactions of R3SbCl2 (R= α- C10H7, cyclo-C6H11) with MY (M= Ag, K, Na; Y= SCN, CN, NCO, N3) yielded the penta- coordinate products, R3Sb (SCN) 2, R3> Sb (NCO) 2,(α-C10H7) 3Sb (CN) 2 and (α-C10 ...