Bulletin of the Chemical Society of Japan

Synthesis and Fluorescence Properties of Selectively Metallated Diporphyrins with Electron-Accepting Moieties.

T Nagata

Index: Nagata, Toshi Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 10 p. 3005 - 3016

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Citation Number: 35

Abstract

Synthesis of selectively metallated diporphyrins with electron-accepting moieties is described. Steady-state fluorescence spectra of these compounds snowed substantial quenching of the fluorescence of the free-base porphyrin. A possible “superexchange” mechanism of long-range electron transfer is discussed.

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