Journal of the American Chemical Society

Secondary Phosphinocarbyne and Phosphaisonitrile Complexes

AL Colebatch, AF Hill

Index: Faraone, F.; Piraino, P.; Marsala, V.; Sergi, S. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 859 - 861

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Citation Number: 10

Abstract

... Journal of the ... Hz)) with a particularly large 1 J PC coupling constant (100.6 Hz), consistent with increased P–C multiple bonding (ie, significant s character) in ... 1.785(11) Å for 3b and 1.771(5) Å in Cummins' dimer(7)). Similar variations in W–C–P bond lengths were calculated for ...