Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The addition of trimethylsilyloxy phosphorus (III) derivatives, generated in situ, to α-haloacrylates and acrylonitriles at room temperature provides a mild, general and stereoselective route to β-phosphonoacrylates. ... The addition of trimethylsilyloxy phosphorus (III) derivatives, ...