Dalton Transactions

Extraction and coordination studies of the unexplored bifunctional ligand carbamoyl methyl sulfoxide (CMSO) with uranium (vi) and cerium (iii) nitrates. Synthesis and …

S Kannan, KV Chetty, V Venugopal, MGB Drew

Index: Kannan, Shanmugaperumal; Chetty, Kuna Venugopal; Venugopal, Venkatarama; Drew, Michael G. B. Dalton Transactions, 2004 , # 21 p. 3604 - 3610

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Citation Number: 15

Abstract

The bifunctional carbamoyl methyl sulfoxide ligands, PhCH2SOCH2CONHPh (L11), PhCH2SOCH2CONHCH2Ph (L22), PhSOCH2CONiPr2 (L33), PhSOCH2CONBu2 (L44), PhSOCH2CONiBu2 (L55) and PhSOCH2CON (C8H17) 2 (L66) have been synthesized and characterized by spectroscopic methods. The selected coordination chemistry of L11, L33, L44 and L55 with [UO2 (NO3) 2] and [Ce (NO3) 3] has been evaluated. The structures of ...