CYCLIC ORGANOPHOSPHORUS COMPOUNDS. PART XV. 1 4-t-BUTYL-2, 6, 7-TRIOXA-1-PHOSPHABICYCLO [2, 2, 2] OCTANE AND ITS OXIDE

RS Edmundson, CI Forth

Index: Edmundson, R. S.; Forth, C. I. Phosphorus and Sulfur and the Related Elements, 1980 , vol. 8, p. 315 - 320

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Citation Number: 11

Abstract

Abstract Treatment of 4-t-butyl-2, 6, 7-trioxa-1-phosphabicyclo [2, 2, 2] octane with sulphuryl chloride yields merely its P-oxide and not the expected 5-t-butyl-2-chloro-5-chloromethyl-1, 3, 2-dioxaphosphorinan 2-oxide. The mass spectra of the bicyclic phosphite and its oxide are discussed.