Tetrahedron letters

Molybdenum (II)-catalyzed allylic substitution

AV Malkov, I Baxendale, DJ Mansfield, P Kočovsky

Index: Malkov, Andrei V.; Baxendale, Ian; Mansfield, Darren J.; Kocovsky, Pavel Tetrahedron Letters, 1997 , vol. 38, # 27 p. 4895 - 4898

Full Text: HTML

Citation Number: 19

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The new Mo(II) triflate complex 5 has been found to catalyze the CC bond forming allylic substitution with silyl enol ethers derived from β-dicarbonyls (eg, 6 + 12 → 14) and from simple ketones (eg, 6 + 13 → 16) as nucleophiles. ... The new Mo(II) triflate complex Mo(CO) 5 (OTf) 2 ...