Journal of Organometallic Chemistry

Some unexpected reactions of perfluoroalkynylmagnesium halides

G Santini, M Le Blanc, JG Riess

Index: Santini,G. et al. Journal of Organometallic Chemistry, 1975 , vol. 102, p. C21 - C24

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Citation Number: 7

Abstract

Abstract RFC CMgX reacts with Ac 2 O to give not only MeC (O) C CR F but also MeC (O) CX C (RF) C (O) Me, and with CF 3 COOPr it gives CF 3 C (O) CH C (OPr) RF not CF 3 C (O) C CR F; RFC CMgBr reacts with Cl 2 to give RFC CBr rather than RFC CCl, while with Br 2 RFC CMgI similarly gives RFC CI rather than RFC CBr.