Cyclopropanes. VIII. 1 Rates of Ring Opening of Substituted Cyclopropyl Ketones and Carbinols2

HM Walborsky, L Plonsker

Index: Walborsky,H.M.; Plonsker,L. Journal of the American Chemical Society, 1961 , vol. 83, p. 2138 - 2144

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Citation Number: 35

Abstract

Examples of the cyclopropylcarbinyl rearrangement can be found in the acid-catalyzed dehydration of cyclopr~ pylcarbinols,~ solvolysis of certain cyclopropylcarbinyl esters and halides, 6 deamination of cyclopropylcarbinyl amines6 and the acid-catalyzed rearrangement of cyclopropyl ketones.'Although the rearrangement of unsubstituted cyclopropylcarbinyl derivatives has been studied kineticallys no systematic kinetic studies ...