Tetrahedron letters

Synthesis of 2, 2-difluoroesters by iododifluoroacetate-copper with organic halides

T Taguchi, O Kitagawa, T Morikawa, T Nishiwaki…

Index: Taguchi, Takeo; Kitagawa, Osamu; Morikawa, Tsutomu; Nishiwaki, Tohru; Uehara, Hideya; et al. Tetrahedron Letters, 1986 , vol. 27, # 50 p. 6103 - 6106

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Citation Number: 96

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... CC bond formation through reactions of iododifluoroacetate-copper with various organic halides in aprotic solvent proceeds effectively to give 2,2-difluoroesters in good yield. With alkenyl iodides, these reactions are stereospecific. ... 2,2-Difluoroesters were effectively ...

~79%

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