Tetrahedron

Biogenetic-type syntheses of isoprenoid and diisoprenoid derivatives of orcinol

G Manners, L Jurd, K Stevens

Index: Manners,G. et al. Tetrahedron, 1972 , vol. 28, p. 2949 - 2959

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Citation Number: 25

Abstract

The products formed by condensation of orcinol with 2-methyl-3-buten-2-ol, with geraniol, and with linaloöl in aqueous solutions of organic acids have been separated and identified. C-isoprenyl-and C-geranyl-orcinols are obtained as major products. Minor amounts of the corresponding hydrates, chromans, chroman hydrates, and hexahydroxanthene derivatives are also formed.