Electroorganic chemistry. 30. A novel acylation of some activated olefins by electroreductive method

T Shono, I Nishiguchi, H Ohmizu

Index: Shono,T. et al. Journal of the American Chemical Society, 1977 , vol. 99, p. 7396 - 7397

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Citation Number: 39

Abstract

4 d12 were obtained from C6D6 i-H2 and C6H6+ D2 with C6H6D6 the major species in both reactions. Both the benzene recovered in the C6H6+ D2 reaction and the hexamethylbenzene ligands in recovered catalyst contained deuterium. Most unexpectedly, the recovered xylenes from a D2 hydrogenation reaction contained large amounts of deuterium and primarily consisted of the do and dl-d6 species with relatively minor ...