Tetrahedron Letters

Aliphatic claisen rearrangement promoted by organoaluminium compounds

K Takai, I Mori, K Oshima, H Nozaki

Index: Takai, Kazuhiko; Mori, Ichiro; Oshima, Koichiro; Nozaki, Hitosi Tetrahedron Letters, 1981 , vol. 22, # 40 p. 3985 - 3988

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Citation Number: 66

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Treatment of allyl vinyl ether derivatives with organoaluminiumamphoteric reagent, R 3 Al or R 2 AlSPn, results in the title reaction at room temperature under uptake of R, H, or SPh as a nucleophile on the aldehydic carbon. ... In sharp contrast, there have been many reports ...