Free-radical rearrangements in the thermal decomposition of tert-butylperoxy 3-(1-phenylcyclopropyl) propanoate, 4-(1-phenylcyclopropyl) butanoate, and 5-(1- …

MP Doyle, PW Raynolds, RA Barents…

Index: Doyle,M.P. et al. Journal of the American Chemical Society, 1973 , vol. 95, p. 5988 - 6000

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Citation Number: 16

Abstract

Abstract: Decomposition of rert-butylperoxy 3-(l-phenylcyclopropyl) propanoate (4), 4-(l- phenylcyclopropyl)-butanoate (141, and 5-(l-phenylcyclopropyl) pentanoate (29) yields the corresponding alkyl radicals which are studied by esr; the barrier to rotation about C, C, for the alkyl radicals produced from 4 and 14 gives a distinct inequivalency in the/3 hydrogens. The yields of assigned products from thermal decomposition of 14 and 29 in benzene are ...

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