The Journal of organic chemistry

Experimental and Computational Study of 6-exo and 7-endo Cyclization of Aryl Radicals Followed by Tandem S RN 1 Substitution

LE Peisino, AB Pierini

Index: Pierini, Adriana B.; Gallego, Mariana H.; Andrada, Karina F. Crespo Journal of Organic Chemistry, 2007 , vol. 72, # 8 p. 3089 - 3092

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Citation Number: 6

Abstract

The reaction of N-allyl-N-(2-halobenzyl)-acetamides and derivatives was investigated in liquid ammonia under irradiation with the nucleophiles Me3Sn–, Ph2P–and O2NCH2–. Following this procedure, novel substituted 2-acetyl-1, 2, 3, 4-tetrahydroisoquinolines and