Inorganic Chemistry

Synthesis, chemistry, and low-temperature crystal and molecular structure of [. mu.-(. eta. 5-cyclopentadienyl) beryllio] octahydropentaborane,[. mu.-(. eta. 5-(C5H5) Be …

DF Gaines, KM Coleson, JC Calabrese

Index: Gaines, Donald F.; Coleson, Kraig M.; Calabrese, Joseph C. Inorganic Chemistry, 1981 , vol. 20, p. 2185 - 2188

Full Text: HTML

Citation Number: 10

Abstract

Reaction of ($-CSH,) BeC1 with KBsHs results in formation of the title compound, which forms crystals in the monoclinic space group P2,/c with u= 10.266 (8) A, b= 5.616 (4) A, c= 16.187 (7) A,/3= 98.50 (5) O, V= 923.0 (5) A', and Z= 4. The low-temperature X-ray structure was solved by direct methods, using anisotropic refinement of positional and temperature factors for nonhydrogen atoms and isotropic refinement for hydrogen atoms, which ...