Inorganic chemistry

Synthesis and spectroscopic properties of platinum (II) terpyridine complexes having an arylborane charge transfer unit

E Sakuda, A Funahashi, N Kitamura

Index: Sakuda, Eri; Funahashi, Akiko; Kitamura, Noboru Inorganic Chemistry, 2006 , vol. 45, # 26 p. 10670 - 10677

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Citation Number: 97

Abstract

Synthesis, redox, spectroscopic, and photophysical properties of a new class of Pt (II) complexes having a phenyl-or duryl (dimesityl) borane group at the 4'-position of a 2, 2': 6', 2''-terpyridine ligand are reported, and the spectroscopic/photophysical characteristics of the complexes are explained by the synergetic effects between Pt (II)-to-ligand charge transfer (CT) and intramolecular CT from the π orbital of the aryl group to the vacant p-orbital on ...