Synthesis of 3-(2, 5-dihydrofuryl)-silanes and-germanes and their transformations under catalytic hydrogenation conditions

…, VN Gevorgyan, YS Goldberg, MV Shymanska

Index: Lukevics, E.; Gevorgyan, V. N.; Goldberg, Y. S.; Shymanska, M. V. Journal of Organometallic Chemistry, 1984 , vol. 263, # 3 p. 283 - 296

Full Text: HTML

Citation Number: 10

Abstract

Abstract A number of 3-triorganosilyl-and 3-trimethylgermyl-2, 5-dihydrofurans have been prepared by the cyclization of 2-triorganosilyl (germyl)-2-butene-1, 4-diols obtained from the hydrosilylation and hydrogermylation products of 1, 4-bis (trimethylsiloxy)-2-butyne. It has been found that the liquid-phase heterogeneous hydrogenation of these compounds over palladium catalysts is accompanied by simultaneous isomerization and disproportionation ...