Tetrahedron Letters

The baeyer-villiger oxidation via carboration, oxidation of 7-acetyl [4.2. 1]-and 7-acetyl [4.2. 2] propellanes

Y Tobe, M Ohtani, K Kakiuchi, Y Odaira

Index: Tobe, Yoshito; Ohtani, Masaru; Kakiuchi, Kiyomi; Odaira, Yoshinobu Tetrahedron Letters, 1983 , vol. 24, # 34 p. 3639 - 3642

Full Text: HTML

Citation Number: 4

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The Baeyer-Villiger oxidation of exo-7-acetyl[4.2.1]- and exo-7-acetyl[4.2.2]propellanes (2X) and (3X) mainly proceeds via unusual carboration intermediates to afford the rearranged products. ... Oxidation of the endo ketones 2N and 3N with m-CPBA gave the ...