Tetrahedron

Epoxy-epimination of cyclic conjugated dienes-VII-: Cycloaddition of nitroso-halogenobenzenes to cyclopentadiene followed by rearrangement to epoxy-epimino-and …

D Rousselle, E Francotte, J Feneau-Dupont, B Tinant…

Index: Rouselle; Francotte; Feneau-Dupont; Tinant; Declercq; Viehe Tetrahedron, 1991 , vol. 47, # 39 p. 8323 - 8330

Full Text: HTML

Citation Number: 4

Abstract

[4+ 2] Cycloaddition of halogenated nitroso benzenes to cyclopentadiene followed by isomerisation of the intermediate adduct occurs already at room temperature to furnish the epoxy-epimine 1 and the epiminopentadienal 2. The structure proof of 1 is based on X-ray analysis.