Molecular Gyroscopes:{Fe (CO) 3} and {Fe (CO) 2 (NO)}+ Rotators Encased in Three??Spoke Stators; Facile Assembly by Alkene Metatheses

T Shima, F Hampel, JA Gladysz

Index: Shima, Takanori; Hampel, Frank; Gladysz Angewandte Chemie - International Edition, 2004 , vol. 43, # 41 p. 5537 - 5540

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Citation Number: 133

Abstract

Molecules that can perform a rotor function are experiencing increasing attention, particularly in the context of nanoscale devices.[1–6] These efforts have evolved far beyond the initial concept stage [7] to materials that are being exploited in nanofluidics and photonics. All rotors consist of a rotator and a stator. Importantly, rotators with electric dipole moments can, in appropriately oriented alternating electric fields, be rendered ...