Preparation and Regioselective SN2'Reaction of Novel g em-Difluorinated Vinyloxiranes with RLi

H Ueki, T Chiba, T Yamazaki…

Index: Blackburn, G. Michael; Kent, David E. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 913 - 918

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Citation Number: 25

Abstract

... The Journal of Organic ... carbon atoms in gem-difluorinated olefins have appeared to possess extraordinarily high electrophilicity due to the strong electronic repulsion between lone ... the anticipated S N 2' product 6b was obtained only in 38% yield as an inseparable E/Z mixture ...