Journal of organometallic chemistry

The behaviour of medium-sized permethylated cyclosilanes towards SOCl 2 and SOCl 2-HC (OCH 3) 3

PK Jenkner, A Spielberger, E Hengge

Index: Jenkner, P.K.; Spielberger, A.; Hengge, E. Journal of Organometallic Chemistry, 1992 , vol. 427, # 2 p. 161 - 164

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Citation Number: 4

Abstract

Abstract Treatment of Si 6 Me 12 with SOCl 2 in various solvents gives α, ω- dichloropermethylpolysilanes (n Si= 2, 3, 4, 6) at temperatures above 80 C. In contrast to an earlier report, treatment of the α, ω-dichloropermethylpolysilanes with HC (OCH 3) 3 in the presence of SOCl 2 does not give Si 6 Me 12.