Tetrahedron

Silyl ketone chemistry: Preparation and reactions of unsaturated silyl ketones

HJ Reich, MJ Kelly, RE Olson, RC Holtan

Index: Reich, Hans J.; Kelly, Martha J.; Olson, Richard E.; Holtan, Ronald C. Tetrahedron, 1983 , vol. 39, # 6 p. 949 - 960

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Citation Number: 95

Abstract

A series of silyl ketones has been prepared by appropriate manipulation of⇌-silylated allenol ethers. Among the compounds prepared were alkenyl, alkynyl and acyl silyl ketones. The spectroscopic properties of representative members of these classes of compounds have been measured, and some of their chemical reactions studied Diels-Alder cycloadditions of vinyl and alkynyl silyl ketones proceed smoothly, and can be used to ...

~80%

~66%

~80%

~52%

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Easy one-step general synthesis of acylsilanes

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