Journal of the American Chemical Society

Highly regio-and stereoselective halohydroxylation reaction of 1, 2-allenyl phenyl sulfoxides. Reaction scope, mechanism, and the corresponding Pd-or Ni-catalyzed …

S Ma, H Ren, Q Wei

Index: Kato,T. et al. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1979 , p. 525 - 528

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Citation Number: 85

Abstract

... smoothly with metallic halides, while the corresponding reaction of 1,2-allenyl sulfoxides must be mediated by certain Al(III) species. ... that of the unsubstituted 1a, and the reactions finished in from 0.3 to 3.2 h at room temperature to give the ... 4, H, H, t-C 4 H 9 (1e), 1.2, 3.2, 87 (E-3ae ...