Journal of fluorine chemistry

Synthesis of pentafluoroseleniumoxide fluorocarbons

CJ Schack, KO Christe

Index: Schack, Carl J.; Christe, Karl O. Journal of Fluorine Chemistry, 1988 , vol. 39, p. 163 - 172

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Citation Number: 2

Abstract

Abstract The reaction of xenon bis-pentafluoroseleniumoxide, Xe (OSeF 5) 2, with the haloolefins, CF 2 CF 2, CF 3 CF CF 2, CF 2 CFCl, and CF 2 CFH, results in the low to moderate yield addition of two SeF 5 O-groups to the double bond. These are the first examples of this type of addition. From cC 5 F 8 and the above olefins these same reaction also gave as products, C 2 F 5 OSeF 5, nC 3 F 7 OSeF 5, cC 5 F 9 OSeF 5, and SeF 5 ...