Synthesis, Structure and Physical Properties of Tetrabutylammonium Salts of Nickel Complexes with the New Ligand dcbdt= 4, 5??dicyanobenzene??1, 2??dithiolate,[Ni ( …

…, D Belo, S Rabaça, EB Lopes, IC Santos…

Index: Simao, Dulce; Alves, Helena; Belo, Dulce; Rabaca, Sandra; Lopes, Elsa Branco; Santos, Isabel Cordeiro; Gama, Vasco; Duarte, Maria Teresa; Henriques, Rui Teives; Novais, Horacio; Almeida, Manuel European Journal of Inorganic Chemistry, 2001 , # 12 p. 3119 - 3126

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Citation Number: 29

Abstract

Abstract The synthesis and characterization of the new aromatic ortho-dithiol, 4, 5- dicyanobenzene-1, 2-dithiol (3) is reported. This compound was used to prepare tetrabutylammonium salts of novel nickel complexes; the nickel (II) salt (nBu 4 N) 2 [Ni (dcbdt) 2](4), the nickel (III) salt (nBu 4 N) 2 [Ni (dcbdt) 2] 2 (5), and the partially oxidized Ni III/IV salt (nBu 4 N) 2 [Ni (dcbdt) 2] 5 (6).(dcbdt= 4, 5-dicyanobenzene-1, 2-dithiolate). The ...