. ALPHA.,. BETA.-Epoxy sulfoxides as useful intermediates in organic synthesis. II. A novel synthesis of. ALPHA.-sulfenylated ketones and. ALPHA.-sulfenylated …

T Satoh, T Kumagawa, K Yamakawa

Index: Satoh, Tsuyoshi; Kumagawa, Takumi; Yamakawa, Koji Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 10 p. 2849 - 2854

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Citation Number: 33

Abstract

Treatment of α, β-epoxy sulfoxides, prepared from 1-chloroalkyl phenyl sulfoxides and carbonyl compounds, with various kinds of alkane-or arenethiolates afforded α-sulfenylated ketones in good yields. This method also offered a novel procedure for a synthesis of α- sulfenylated aldehydes.