Journal of Organometallic Chemistry

Selectivity in the reactions of alkyllithium reagents with α, ω-dichloropermethylsiloxanes

SA Kazoura, WP Weber

Index: Kazoura, Samih Amine; Weber, Wolliam P. Journal of Organometallic Chemistry, 1983 , vol. 243, # 2 p. 149 - 156

Full Text: HTML

Citation Number: 3

Abstract

Abstract The reactions of 1, 3-dichlorotetramethyldisiloxane and 1, 5- dichlorohexamethyltrisiloxane with alkyllithium reagents have been studied. At low temperature (− 78 C) only one of the two silicon-chlorine bonds of 1, 3-