Journal of Organometallic Chemistry

Polyhalo-organometallic and-organometalloidal compounds XIII. Some pentahalophenyl-substituted polysilanes

PJ Morris, H Gilman

Index: Morris,P.J.; Gilman,H. Journal of Organometallic Chemistry, 1968 , vol. 11, p. 463 - 469

Full Text: HTML

Citation Number: 0

Abstract

Until recently the only pentachlorophenyl-silicon compound reported in the literature was (pentachIorophenyl) trichlorosilane, formed in low yield by the catalytic chlorination of phenyltrichforosilane'. The preparation of pentafluorophenylmagnesium halides2m3 and pentafluorophenyllithium~*' led to the formation of silnnes con tainingoneor more pen tafiuorophenylgroups directly bonded to a silicon a tom”*-. By the use of ...