Organotin dithiocarbamates: single-source precursors for tin sulfide thin films by aerosol-assisted chemical vapor deposition (AACVD)

…, MA Malik, J Raftery, PP Edwards, P O'Brien

Index: Ramasamy, Karthik; Kuznetsov, Vladimir L.; Gopal, Kandasamy; Malik, Mohammad A.; Raftery, James; Edwards, Peter P.; O'Brien, Paul Chemistry of Materials, 2013 , vol. 25, # 3 p. 266 - 276

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Citation Number: 47

Abstract

A series of diorganotin complexes of dithiocarbamates [Sn (C4H9) 2 (S2CN (RR′) 2) 2](R, R′= ethyl (1); R= methyl, R′= butyl (2); R, R′= butyl (3); R= methyl, R′= hexyl (4); and [Sn (C6H5) 2 (S2CN (RR′) 2) 2](R, R′= ethyl (5); R= methyl, R′= butyl (6); R, R′= butyl (7); R= methyl, R′= hexyl (8) were synthesized. Single-crystal X-ray structures of 2, 3, and 8 were determined. Thermogravimetric analysis (TGA) showed single-step decomposition ...