Direct chemical and electrochemical syntheses of coordination compounds of benzazolyl azo ligands

…, SA Mashchenko, AI Uraev, DA Garnovskii…

Index: Burlov, Anatolii S.; Antsyshkina, Alla S.; Sadikov, Georgii G.; Koshchienko, Yurii V.; Divaeva, Ludmila N.; Mashchenko, Sergei A.; Uraev, Ali I.; Garnovskii, Dmitrii A.; Vasilchenko, Igor S.; Vlasenko, Valery G.; Zubavichus, Yan V.; Borodkin, Gennadii S.; Kharisov, Boris I.; Hernandez Garcia, Tomas C.; Sergienko, Vladimir S.; Garnovskii, Alexander D. Journal of Coordination Chemistry, 2010 , vol. 63, # 6 p. 917 - 930

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Citation Number: 4

Abstract

The chelates of 2-hydroxy (aminophenylnaphthyl)-azo-1-alkylbenzimidazoles were obtained from electrochemical (anodic dissolution of zero-valent d-metals) and chemical (from acetates of the same metals) syntheses in methanol. The EXAFS and X-ray single crystal diffraction data revealed the existence of octahedral nickel, zinc, and cadmium complexes containing four five-membered metallocycles with the N4О2 or N6 ligand environments. ...