Restricted Rotation in Aryl Amines. XV. Stereoisomeric Diglutarimidomesitylenes

R Adams, DC Blomstrom

Index: Adams; Blomstrom Journal of the American Chemical Society, 1953 , vol. 75, p. 2375

Full Text: HTML

Citation Number: 2

Abstract

Bis-(a, a-dimethylglutarimid0)-mesitylene (IV) has been prepared and separated into two forms which are shown to be &-trans isomers by infrared spectra and by nitration to give an analogous pair of stereoisomeric nitro compounds. The previously reported explanation of the absence of isomerism in homologous five-membered ring compounds is thus conkmed.